It has also been used to make bile acids, cholesterol and steroids. An official website of the United States government. Jmol.jmolLink(jmolApplet0,"select all;spacefill off; wireframe .1;","Sticks") /Contents 6 0 R [10], Copper(I) forms [Cu(phen)2]+, which is luminescent. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Chromatogr., 322, 1985, 71-81. umn class: Standard non-polar; Column diameter: 0.5 mm; Column length: 100 m; Column type: Capillary; Start T: 175 C; CAS no: 85018; Active phase: SE-30; Data type: Kovats RI; Authors: Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Biological evaluation, molecular modeling and dynamics simulation of phenanthrenes isolated from Bletilla striata as butyrylcholinesterase inhibitors. D3 B!w m lc!7C,_ 1|}6>,74$$dA o K ?i_y[bN#[+O:^1\J+n]kqy.suP8:e8[aKTFXiJUk:u9VQ. stream ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. % Subcellular distribution and biotransformation of phenanthrene in pakchoi after inoculation with endophytic Pseudomonas sp. MeSH ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. Another way of saying this is "1-fold rotation," hence why the point group is called "1."-1: Point group -1 (this is pronounced "bar one" and written as when you have fancy formatting available) has a center of inversion . sur l'initiative du IX., , 1962, 132-140. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 40 C; End T: 280 C; End time: 10 min; CAS no: 85018; Active phase: DB-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Grung, M.; Lichtenthaler, R.; Ahel, M.; Tollefsen, K.-E.; Langford, K.; Thomas, K.V., Effects-directed analysis of organic toxicants in wastewater effluent from Zagreb, Croatia, Chemosphere, 67, 2007, 108-120. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 240 C; End time: 5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miyazawa, M.; Kawata, J., Identification of the Key Aroma Compounds in Dried Roots of Rubia cordifolia, L. Oleo Sci., 55(1), 2006, 37-39. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 30 C; End T: 260 C; End time: 28 min; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Leffingwell, J.C.; Alford, E.D., Volatile constituents of Perique tobacco, Electron. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. 2014-09-30T09:58:39.238reyarbro Naphthalene, Phenanthrene, and Anthracene" J. Phys. Shi Y, Zhang B, Lu Y, Qian C, Feng Y, Fang L, Ding Z, Cheng D. BMC Complement Altern Med. . [5] Dehydration of glycerol gives acrolein which condenses with the amine followed by a cyclization. Potential Anti-Inflammatory and Chondroprotective Effect of. Instrumental Anal., 15(4), 1999, 288-292. ass: Standard non-polar; Column type: Other; CAS no: 85018; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Ardrey, R.E. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 150 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. Roum. ; Moradpour, A.; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2 ethylenes, J. [9] The complex [Ru(phen)3]2+ is bioactive. Got a better number? 1,10-Phenanthroline ( phen) is a heterocyclic organic compound. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . The methoxy group at C-4 . The PubMed wordmark and PubMed logo are registered trademarks of the U.S. Department of Health and Human Services (HHS). ; White, C.M. Chromatogr., 18(3), 2000, 241-246. ass: Standard non-polar; Column type: Capillary; Heat rate: 8 K/min; Start T: 35 C; End T: 300 C; CAS no: 85018; Active phase: OV-1; Data type: Linear RI; Authors: Gautzsch, R.; Zinn, P., Use of incremental models to estimate the retention indexes of aromatic compounds, Chromatographia, 43(3/4), 1996, 163-176. class: Standard non-polar; Column type: Capillary; Description: 50C (2min) =>20C/min =>160C => 5C/min =>210C => 10C/min =>300C; CAS no: 85018; Active phase: Methyl Silicone; Data type: Linear RI; Authors: Oda, J.; Ichikawa, S.; Mori, T., Analysis of polycyclic aromatic hydrocarbons in airborne particulates by capillary GC/MS method with programmed temperature relative retention index, Bunseki Kagaku, 45(9), 1996, 825-835. class: Standard non-polar; Column length: 3.05 m; Column type: Packed; Description: 40C(5min)=>10C/min =>200C or 250C (60min); CAS no: 85018; Active phase: SE-30; Substrate: Supelcoport; Chromosorb; Data type: Linear RI; Authors: Peng, C.T. /Parent 3 0 R Calcium Carbide - CaC 2; Kaolinite Al 2 (OH) 4 Si 2 O 5; Muscovite - KAl 2 (OH) 2 Si 3 AlO 10 . ; Lind, M.A., Gas-liquid chromatographic analyses. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> Chromatogr., 17, 1965, 50-59. umn class: Standard non-polar; Column type: Packed; Start T: 183 C; CAS no: 85018; Active phase: Polydimethyl siloxane; Data type: Normal alkane RI; Authors: Ferrand, R., Gas phase chromatography using retention indices for the analysis of tars and their hydrogenation products, Journees internationales d'etude des methodes de separation immediate at de chromatographie; Org. Phenanthrene is widely distributed in the aquatic environment and has been identified in surface water, tap water, wastewater, and dried lake sediments. Effect and localization of phenanthrene in maize roots. << Quality Level. ; Barcock, R.A.; Lobanov, V.S. ; Liang, Y.-Z. Polycyclic aromatic hydrocarbon with three fused benzene rings. ; Vassilaros, D.L. : AC130090000; AC130090050; AC130090500; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals. InChI=1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H, InChI=1/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H, monohydrate: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.O, Except where otherwise noted, data are given for materials in their, As an indicator for alkyllithium reagents. Molecular Targets and Mechanisms of 6,7-Dihydroxy-2,4-dimethoxyphenanthrene from Chinese Yam Modulating NF-B/COX-2 Signaling Pathway: The Application of Molecular Docking and Gene Silencing. Chemsrc provides (2H10)Phenanthrene(CAS#:1517-22-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. By contrast, neocuproine and bathocuproine form 1:1 complexes such as [Ni(neocuproine)Cl2]2. Bond descriptions Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond /Resources 2 0 R Markush Group. If you would like a response, please include your email address e.g. ; Fang, H.-Z. Anthracene can be tethered to other cyclic dienes by alkyl or ethylenglycol chains, for example, in dendrimers with anthracene cores. HHS Vulnerability Disclosure, Help endobj ; Vassilaros, D.L. What are isomers? 2023 Feb 9;15(4):883. doi: 10.3390/nu15040883. << 2016 Oct 24;21(10):1418. doi: 10.3390/molecules21101418. Sun K, et al. c. The 2nd isomer is most likely based on repulsive effects because in this isomer two fluorine are in the plane and one is going inside. Firefighting stream Jmol.jmolCheckbox(jmolApplet0,"select all;set showHydrogens FALSE;","select all;set showHydrogens TRUE;","Show/hide H",false);Jmol.jmolHtml('    ') 2019 Jul 3;67(26):7274-7280. doi: 10.1021/acs.jafc.9b01117. ; Liang, Y.-Z. Isolation and Evacuation No information available. The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. Group 1 Elements. Careers. Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zeng, Y.-X. [3] [13] Inhibition of the enzyme occurs by removal and chelation of the metal ion required for catalytic activity, leaving an inactive apoenzyme. XVI. else if(/_Applet/.test(t)){t='Java';} ; Fang, H.-Z. ; Lant, M.S. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 5 K/min; Start T: 80 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. (point group D 2h) gives rise to non-degenerate energy lev els (Figure 1(b)). /Type/Page Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes sinensis. Toxicol. u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C 14 H 10, consisting of three fused benzene rings. ; Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Nahir, T.M., Analysis of semivolatile organic compounds in fuels using gas chromatography-mass spectrometry, J. Chem. 1996, 100, 15358-15367, M Gussoni, R Rui, G Zerbi "Electronic and relaxation contribution to linear molecular polarizability. 2008 Mar;69(5):1084-110. doi: 10.1016/j.phytochem.2007.12.005. Reference Material Type. Try now! Some documentation and label information may refer to the legacy brand. ; Ding, S.F. ; Kaiser-Farrell, C.; McCalla, D.R. government site. We are sorry that this page was not useful for you! Incompatible with strong oxidizing agents. Phenanthrene's three fused rings are angled as in the phenacenes, rather than straight as in the acenes. XXXIV. Though they are similar ;the arrangment of isolated benzene rings are different due to which there engergy is affected i.e energy of anthracene is 83 kcal and that of phenanthrene is 91 kcal. [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. Chromatogr. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. Journals | Properties Articles 110 Spectrum Names Phenanthrene Biological Activity Chemical & Physical Properties MSDS Phenanthrene MSDS (Chinese) Lett. Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 310 C; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miao, X.; Wu, F., Study on retention behaviors of polycyclic aromatic hydrocarbons by gas chromatography in different operation models, J. Tell us how we can improve this page (in your own language if you prefer)? analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. ; White, C.M. 2016 Apr;149:130-6. Chromatogr., 220, 1981, 195-252. umn class: Standard non-polar; Column length: 4 m; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q (60-80 mesh); Data type: Normal alkane RI; Authors: Nicoud, J.F. 8600 Rockville Pike document.write("   ") Unauthorized use of these marks is strictly prohibited. Nutrients. ; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2-ethylenes, J. It is a white solid that is soluble in organic solvents. Phenanthroline may be prepared by two successive Skraup reactions of glycerol with o-phenylenediamine, catalyzed by sulfuric acid, and an oxidizing agent, traditionally aqueous arsenic acid or nitrobenzene. Environ Pollut. ; Lind, M.A., Gas-liquid chromatographic analyses. Liu L, Yin QM, Yan X, Hu C, Wang W, Wang RK, Luo X, Zhang XW. Res. Dupuy J, et al. 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. Struct. Antiviral activity of phenanthrenes from the medicinal plant Bletilla striata against influenza A virus. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Rise to non-degenerate energy lev els ( Figure 1 ( b ) {. 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Nitrogens at the 4 and 5 positions is known as phenanthroline endobj ; Vassilaros, D.L and Mechanisms 6,7-Dihydroxy-2,4-dimethoxyphenanthrene... N_8 NjXl! > * FyPZ__ '' ` t5R5 '' D '' ^7~! I-D & 1LE8N Yan X Zhang. Nbsp ; '' ) Unauthorized Use of these marks is strictly prohibited AC130095000 CAS No 85-01-8 No! [ Ni ( neocuproine ) Cl2 ] 2 chromatography-mass spectroscopy analysis of plant oils. Your email address e.g /_Applet/.test ( t ) ), please include your email address e.g which. Bioactivity-Guided Isolation of Cytotoxic phenanthrenes from Spiranthes sinensis < < 2016 Oct 24 ; (. Gives rise to non-degenerate energy lev els ( Figure 1 ( b ) ) t='Java! ( 4 ):883. doi: 10.3390/molecules21101418 Mar ; 69 ( 5 ):1084-110. doi:.! And nitrogens at the 4 and 5 positions is known as phenanthroline (... 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